Maximum likelihood estimates of the parameters are calculated by maximizing the likelihood function with respect to the parameters. The likelihood function describes, for each set of distribution parameters, the chance that the true distribution has those parameters based on the sample data.
Minitab uses the Newton-Raphson algorithm1 to calculate maximum likelihood estimates of the parameters that define the distribution. The Newton-Raphson algorithm is a recursive method for computing the maximum of a function. All resulting functions, such as the percentiles and survival probabilities, are calculated from that distribution.
For some data, the likelihood function is unbounded and, therefore, yields inconsistent estimates for distributions with a threshold parameter (such as the 2-parameter exponential, 3-parameter Weibull, 3-parameter lognormal, and 3-parameter loglogistic distributions). In these cases, the usual maximum likelihood estimation method can break down. When this happens, Minitab assumes a fixed threshold parameter using a bias correction algorithm and finds the maximum likelihood estimates of the other two parameters. For more information, see references 2, 3, 4, and 5.
Least squares estimates are calculated by fitting a regression line to the points in a probability plot from a data set that has the minimal sum of the deviations squared (least square error). The line is formed by regressing either the time to failure or the logarithm of the time to failure (X) to the transformed percent (Y).
For information on how the assumption of common shape or scale parameters affects the LSE or MLE estimates, go to Least squares estimation method and maximum likelihood estimation method and click "Assume common shape or scale parameters for parametric distribution analysis".